Issue 16, 2022

Tunable photosalient behaviours within coordination polymers via functional molecular prearrangements

Abstract

Four Cd(II)/diene coordination polymers (CPs) with similar 1D chain motifs exhibit different photosalient (PS) behaviours in response to UV light. The [2+2] photoreaction between the C[double bond, length as m-dash]C groups within these CPs results in diverse PS behaviours of their crystals with different C[double bond, length as m-dash]C pair arrangements. The interesting PS behaviours of these CPs can be applied in design and fabrication of advanced photoactuating materials.

Graphical abstract: Tunable photosalient behaviours within coordination polymers via functional molecular prearrangements

Supplementary files

Article information

Article type
Communication
Submitted
20 дек. 2021
Accepted
26 јан. 2022
First published
26 јан. 2022

Chem. Commun., 2022,58, 2674-2677

Tunable photosalient behaviours within coordination polymers via functional molecular prearrangements

J. Wu, B. Long, M. Wang, D. J. Young, F. Hu, Y. Mi and J. Lang, Chem. Commun., 2022, 58, 2674 DOI: 10.1039/D1CC07139D

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