Issue 53, 2017
From the journal:

Chemical Communications

Exhaustive Suzuki–Miyaura reactions of polyhalogenated heteroarenes with alkyl boronic pinacol esters†

Sébastien Laulhé,‡a   J. Miles Blackburn‡b  and  Jennifer L. Roizen ORCID logo *b  

* Corresponding authors

a Department of Chemistry and Chemical Biology, IUPUI, Indianapolis, IN 46202, USA

b Duke University, Department of Chemistry, Box 90346, Durham, North Carolina 27708-0354, USA
E-mail: j.roizen@duke.edu

Abstract

A novel Suzuki–Miyaura protocol is described that enables the exhaustive alkylation of polychlorinated pyridines. This method facilitates a formal synthesis of normuscopyridine and the rapid assembly of a dumbbell shaped portion of a [2]rotaxane.

Graphical abstract: Exhaustive Suzuki–Miyaura reactions of polyhalogenated heteroarenes with alkyl boronic pinacol esters

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Article information

DOI
https://doi.org/10.1039/C7CC00997F
Article type
Communication
Submitted
07 фев. 2017
Accepted
28 фев. 2017
First published
03 мар. 2017

Chem. Commun., 2017,53, 7270-7273

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Exhaustive Suzuki–Miyaura reactions of polyhalogenated heteroarenes with alkyl boronic pinacol esters

S. Laulhé, J. M. Blackburn and J. L. Roizen, Chem. Commun., 2017, 53, 7270 DOI: 10.1039/C7CC00997F

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