Issue 53, 2017

Reversible dinitrogen binding to [Cp′Fe(NHC)] associated with an N2-induced spin state change

Abstract

The 15-valence electron (VE), high-spin (S = 3/2) half-sandwich complex [Cp′Fe(IiPr2Me2)] (3; IiPr2Me2 = 1,3-di-iso-propyl-4,5-dimethylimidazol-2-yildene) reversibly coordinates N2 to form the 17VE, low-spin (S = 1/2) compound [Cp′Fe(IiPr2Me2)(η1-N2)] (4).

Graphical abstract: Reversible dinitrogen binding to [Cp′Fe(NHC)] associated with an N2-induced spin state change

Supplementary files

Article information

Article type
Communication
Submitted
27 Feb 2017
Accepted
03 Apr 2017
First published
10 Apr 2017

Chem. Commun., 2017,53, 7274-7277

Reversible dinitrogen binding to [Cp′Fe(NHC)] associated with an N2-induced spin state change

M. Reiners, D. Baabe, M. Zaretzke, M. Freytag and M. D. Walter, Chem. Commun., 2017, 53, 7274 DOI: 10.1039/C7CC01535F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements