Issue 66, 2012
From the journal:

Chemical Communications

Donor–acceptor stabilized silaformyl chloride†‡

Rajendra S. Ghadwal,*a   Ramachandran Azhakar,a   Herbert W. Roesky,*a   Kevin Pröpper,a   Birger Dittrich,*a   Catharina Goedeckeb  and  Gernot Frenking*b  

* Corresponding authors

a Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany
E-mail: rghadwal@uni-goettingen.de, hroesky@gwdg.de, bdittri@gwdg.de

b Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, 35032 Marburg, Germany
E-mail: frenking@chemie.uni-marburg.de

Abstract

Formyl chloride (H(Cl)C[double bond, length as m-dash]O) is unstable at room temperature and decomposes to HCl and CO. Silicon analogue of formyl chloride, silaformyl chloride IPr·SiH(Cl)[double bond, length as m-dash]O·B(C6F5)3 (3) (IPr = 1,3-bis(2,6-diisopropyl-phenyl)imidazol-2-ylidene), was stabilized by Lewis donor–acceptor ligands. Compound 3 is not only the first stable acyclic silacarbonyl compound but also the first silacarbonyl halide reported so far.

Graphical abstract: Donor–acceptor stabilized silaformyl chloride

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC32887A
Article type
Communication
Submitted
23 апр. 2012
Accepted
02 јул. 2012
First published
02 јул. 2012

Chem. Commun., 2012,48, 8186-8188

Permissions

Request permissions

Donor–acceptor stabilized silaformyl chloride

R. S. Ghadwal, R. Azhakar, H. W. Roesky, K. Pröpper, B. Dittrich, C. Goedecke and G. Frenking, Chem. Commun., 2012, 48, 8186 DOI: 10.1039/C2CC32887A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements