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Issue 66, 2012
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CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine

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Abstract

Photocatalytic CO2 reduction has been studied for two dyads with porphyrin covalently attached to rhenium tricarbonyl bipyridine moieties, and on separate components consisting of [Re(CO)3(Picoline)Bpy]+ and either zinc porphyrin or zinc chlorin. TONs decrease in the order: zinc porphyrin + Re > long spacer dyad > zinc chlorin + Re > short spacer dyad.

Graphical abstract: CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine

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Publication details

The article was received on 08 May 2012, accepted on 18 Jun 2012 and first published on 19 Jun 2012


Article type: Communication
DOI: 10.1039/C2CC33308B
Citation: Chem. Commun., 2012,48, 8189-8191

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    CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine

    C. D. Windle, M. V. Câmpian, Anne-K. Duhme-Klair, E. A. Gibson, R. N. Perutz and J. Schneider, Chem. Commun., 2012, 48, 8189
    DOI: 10.1039/C2CC33308B

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