Issue 1, 2024

A trinuclear metallasilsesquioxane of uranium(iii)

Abstract

The silsesquioxane ligand (iBu)7Si7O9(OH)3 (iBuPOSSH3) is revealed as an attractive system for the assembly of robust polynuclear complexes of uranium(III) and allowed the isolation of the first example of a trinuclear U(III) complex ([U3(iBuPOSS)3]) that exhibits magnetic communication and promotes dinitrogen reduction in the presence of reducing agent.

Graphical abstract: A trinuclear metallasilsesquioxane of uranium(iii)

Supplementary files

Article information

Article type
Communication
Submitted
01 Nov. 2023
Accepted
22 Nov. 2023
First published
23 Nov. 2023

Chem. Commun., 2024,60, 55-58

A trinuclear metallasilsesquioxane of uranium(III)

M. Tricoire, N. Jori, F. Fadaei Tirani, R. Scopelliti, I. <img border="0" src="https://www.rsc.org/images/entities/char_005a_0306.gif" alt="[Z with combining breve]" xmlns="http://www.rsc.org/schema/rscart38" />ivković, L. S. Natrajan and M. Mazzanti, Chem. Commun., 2024, 60, 55 DOI: 10.1039/D3CC05390C

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