Issue 36, 2018

Solvent-induced ion separation of a beryllium scorpionate complex

Abstract

Spontaneous ion separation of the scorpionate beryllium complex, TpBeI 1 (Tp = 1-trispyrazolylborate), occurs upon treatment with THF, yielding [TpBe(thf)]I 2, which was characterized by heteronuclear NMR spectroscopy (1H, 9Be, 13C) and structurally characterized by single crystal X-ray diffraction. 2 represents a rare example of a structurally characterized monocationic beryllium complex, and to the best of our knowledge, the synthesis of 2 by a solvent-induced ion separation has previously only been observed in the reactions of beryllium dihalides with strong Lewis bases.

Graphical abstract: Solvent-induced ion separation of a beryllium scorpionate complex

Supplementary files

Article information

Article type
Communication
Submitted
24 Apr. 2018
Accepted
09 Maijs 2018
First published
11 Maijs 2018

Dalton Trans., 2018,47, 12511-12515

Solvent-induced ion separation of a beryllium scorpionate complex

D. Naglav, B. Tobey, K. Dzialkowski, D. Bläser, C. Wölper, G. Jansen and S. Schulz, Dalton Trans., 2018, 47, 12511 DOI: 10.1039/C8DT01640B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements