Issue 77, 2018

Ultrasound-induced gelation of a giant macrocycle

Abstract

A 68-membered macrocycle undergoes ultrasound-induced supramolecular gelation in acetonitrile. The sonogel shows a remarkable thermostability, indicating that self-assembly is mediated by exceptionally robust non-covalent interactions. Model compounds indicate that the macrocyclic topology is essential for gelation to occur.

Graphical abstract: Ultrasound-induced gelation of a giant macrocycle

Supplementary files

Article information

Article type
Communication
Submitted
13 Jūn. 2018
Accepted
24 Jūl. 2018
First published
11 Sept. 2018
This article is Open Access
Creative Commons BY license

Chem. Commun., 2018,54, 10874-10877

Ultrasound-induced gelation of a giant macrocycle

D. Núñez-Villanueva, M. A. Jinks, J. Gómez Magenti and C. A. Hunter, Chem. Commun., 2018, 54, 10874 DOI: 10.1039/C8CC04742A

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