Issue 82, 2017

[Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]: the longest intermetalloid chain compound of tin

Abstract

The reaction of the metalloid tin cluster [Sn10(Hyp)4]2− with (Ph3P)Au-SHyp (Hyp = Si(SiMe3)3) gave an intermetalloid cluster [Au3Sn18(Hyp)8]1, which is the longest intermetalloid chain compound of tin to date. 1 shows a structural resemblance to binary AuSn phases, which is expected for intermetalloid clusters.

Graphical abstract: [Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]−: the longest intermetalloid chain compound of tin

Supplementary files

Article information

Article type
Communication
Submitted
07 Sept. 2017
Accepted
23 Sept. 2017
First published
25 Sept. 2017

Chem. Commun., 2017,53, 11314-11317

[Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]: the longest intermetalloid chain compound of tin

M. Binder, C. Schrenk, T. Block, R. Pöttgen and A. Schnepf, Chem. Commun., 2017, 53, 11314 DOI: 10.1039/C7CC07029B

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