Issue 16, 2020

Electrodeposition of nickel nanostructures using silica nanochannels as confinement for low-fouling enzyme-free glucose detection

Abstract

This work reports an enzyme-free glucose sensor based on nickel nanostructures electrodeposited on a fluorine-doped tin oxide (FTO) electrode modified with a silica nanochannel membrane (SNM). The SNM consists of a high density of nanochannels vertically oriented to the electrode surface, which can spatially confine the electrodeposition of nickel nanostructures and protect them to make Ni@SNM/FTO electrodes. In alkaline media, nickel could be converted to nickel oxyhydroxide that displayed catalytic activity toward the anodic oxidation of glucose. The electrodes could thus function as enzyme-free sensors for glucose detection. Under optimal conditions, the sensors exhibited an excellent analytical performance, with an analytical sensitivity as high as 62.3 μA mM−1 cm−2, a wide detection range from 10 μM to 12 mM and a low detection limit of 0.44 μM. Furthermore, given nickel nanostructures were embedded inside the nanochannels of the SNM (with a diameter of 2–3 nm), the sensor possessed anti-fouling ability and outstanding current stability, thus allowing the direct detection of glucose in dilute blood samples.

Graphical abstract: Electrodeposition of nickel nanostructures using silica nanochannels as confinement for low-fouling enzyme-free glucose detection

  • This article is part of the themed collection: Biosensors

Supplementary files

Article information

Article type
Paper
Submitted
04 Nov 2019
Accepted
13 Des 2019
First published
14 Des 2019

J. Mater. Chem. B, 2020,8, 3616-3622

Electrodeposition of nickel nanostructures using silica nanochannels as confinement for low-fouling enzyme-free glucose detection

J. Ding, X. Li, L. Zhou, R. Yang, F. Yan and B. Su, J. Mater. Chem. B, 2020, 8, 3616 DOI: 10.1039/C9TB02472G

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