Issue 5, 2016

Synthesis and structure of the extended phosphazane ligand [(1,4-C6H4){N(μ-PNtBu)2NtBu}2]4−

Abstract

The reaction of the phenylene-bridged precursor (1,4-C6H4)[N(PCl2)2]2 with tBuNH2 in the presence of Et3N gives the new ligand precursor (1,4-C6H4)[N(μ-NtBu)2(PNHtBu)2]2, deprotonation of which with Bu2Mg gives the novel tetraanion [(1,4-C6H4){N(μ-NtBu)2(PNtBu)2}2]4−.

Graphical abstract: Synthesis and structure of the extended phosphazane ligand [(1,4-C6H4){N(μ-PNtBu)2NtBu}2]4−

Supplementary files

Article information

Article type
Communication
Submitted
06 Nov 2015
Accepted
01 Dez 2015
First published
03 Dez 2015

Dalton Trans., 2016,45, 1868-1871

Author version available

Synthesis and structure of the extended phosphazane ligand [(1,4-C6H4){N(μ-PNtBu)2NtBu}2]4−

R. Sevilla, R. J. Less, R. García-Rodríguez, A. D. Bond and D. S. Wright, Dalton Trans., 2016, 45, 1868 DOI: 10.1039/C5DT04393J

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