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Abstract | Cited by

The frustrated Lewis pair comprised of B(C6F5)3 and a boryl–borate lithium salt Li[pinBB(Ph)pin] can efficiently activate dihydrogen, pinacolborane and ethylene at ambient temperature. Theoretical studies suggest that the nucleophilic sp2 boryl moiety of Li[pinBB(Ph)pin] plays different roles in these reactions.

Graphical abstract: Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H–H, B–H and C [[double bond, length as m-dash]] C bonds with B(C6F5)3 and boryl–borate lithium

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