Issue 8, 2022

Co-Catalyzed C(sp3)–C(sp2) bond cleavage via hydrogen atom transfer

Abstract

The discovery of a new Co-catalyzed hydrogen atom transfer (HAT) C(sp3)–C(sp2) bond cleavage method to access ketones from alkenes is reported. This unprecedented transformation features mild reaction conditions and good functional group compatibility, and it proceeds through a key alkoxy radical formation and subsequent β-fragmentation approach.

Graphical abstract: Co-Catalyzed C(sp3)–C(sp2) bond cleavage via hydrogen atom transfer

Supplementary files

Article information

Article type
Research Article
Submitted
24 جنؤری 2022
Accepted
05 مارٕچ 2022
First published
08 مارٕچ 2022

Org. Chem. Front., 2022,9, 2135-2140

Co-Catalyzed C(sp3)–C(sp2) bond cleavage via hydrogen atom transfer

B. Zhou, D. Tian, J. An, Y. Zhou, R. Yan, H. Song, X. Liu and Y. Qin, Org. Chem. Front., 2022, 9, 2135 DOI: 10.1039/D2QO00125J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements