Issue 13, 2024

A tetravalent praseodymium complex with field-induced slow magnetic relaxation

Abstract

Herein the synthesis, structural characterization, and magnetic properties of a Pr(IV) complex [Pr(OSiPh3)4(L)] (1, L = 4,4′-dimethoxy-2,2′-bipyridine) are reported. The stability of the Pr(IV) complex significantly enhanced with the use of the bidentate ligand L. Slow magnetic relaxation was observed at low temperatures, indicating that the complex may be the first single-ion magnet with a tetravalent lanthanide ion being the magnetic center.

Graphical abstract: A tetravalent praseodymium complex with field-induced slow magnetic relaxation

Supplementary files

Article information

Article type
Communication
Submitted
08 جنؤری 2024
Accepted
05 مارٕچ 2024
First published
06 مارٕچ 2024

Dalton Trans., 2024,53, 5779-5783

A tetravalent praseodymium complex with field-induced slow magnetic relaxation

T. Xue, Y. Ding and Z. Zheng, Dalton Trans., 2024, 53, 5779 DOI: 10.1039/D4DT00052H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements