Green synthesis of MOF-based textile composites for the degradation of a chemical warfare agent simulant

Nelly Couzon; Pauline Hardy; Manuela Ferreira; Nisrine Hammi; Jérémy Dhainaut; Frédérique Pourpoint; Sébastien Royer; Thierry Loiseau; Christine Campagne; Christophe Volkringer

doi:10.1039/D3DT03359G

Green synthesis of MOF-based textile composites for the degradation of a chemical warfare agent simulant†

Nelly Couzon,^a Pauline Hardy,^a Manuela Ferreira,^b Nisrine Hammi,^a Jérémy Dhainaut,

^a Frédérique Pourpoint,^a Sébastien Royer,

^a Thierry Loiseau,

^a Christine Campagne^b and Christophe Volkringer

*^a

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* Corresponding authors

^a Univ. Lille, CNRS, Centrale Lille, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, F-59000 Lille, France
E-mail: christophe.volkringer@centralelille.fr

^b Univ. Lille, Univ. Lille, ENSAIT, ULR 2461–GEMTEX–Génie et Matériaux Textiles, F-59000 Lille, France

Abstract

A green synthesis of UiO-66-NH₂ embedded in chitosan and deposited on textiles has been investigated for the degradation of chemical warfare agents. This method requires no heating or use of toxic solvents. The composite synthesized presents an interesting efficiency in detoxifying common simulants of chemical warfare agents, such as DMNP. In parallel, resistance and permeability tests were also realized in order to confirm the suitability of the composites for further applications.

Dalton Transactions

Green synthesis of MOF-based textile composites for the degradation of a chemical warfare agent simulant†

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Green synthesis of MOF-based textile composites for the degradation of a chemical warfare agent simulant

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