Issue 53, 2017

Photoisomerisation and light-induced morphological switching of a polyoxometalate–azobenzene hybrid

Abstract

The functionalization of a spherical Keplerate-type polyoxometalate {Mo72V30} with a cationic azobenzene surfactant has been achieved through ionic self-assembly. The photoisomerisation reaction of this complex, which emerges in a light-triggered aggregation–disaggregation process, has been followed by 1H NMR spectroscopy, dynamic light scattering, absorption spectroscopy and scanning electron microscopy analyses.

Graphical abstract: Photoisomerisation and light-induced morphological switching of a polyoxometalate–azobenzene hybrid

Supplementary files

Article information

Article type
Communication
Submitted
09 مارٕچ 2017
Accepted
10 اپریل 2017
First published
10 اپریل 2017

Chem. Commun., 2017,53, 7278-7281

Photoisomerisation and light-induced morphological switching of a polyoxometalate–azobenzene hybrid

G. Markiewicz, D. Pakulski, A. Galanti, V. Patroniak, A. Ciesielski, A. R. Stefankiewicz and P. Samorì, Chem. Commun., 2017, 53, 7278 DOI: 10.1039/C7CC01805C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements