Issue 39, 2023

Ultra-selective, ultra-clean 1D rotating-frame Overhauser effect spectroscopy

Abstract

An ultra-selective 1D NMR experiment – GEMSTONE-ROESY – enables clear, unambiguous assignment of ROE signals in the not uncommon situation that traditional selective methods fail. Its usefulness is demonstrated in the analysis of the natural products cyclosporin and lacto-N-difucohexaose I, providing detailed insight into the structures and conformations of these molecules.

Graphical abstract: Ultra-selective, ultra-clean 1D rotating-frame Overhauser effect spectroscopy

Supplementary files

Article information

Article type
Communication
Submitted
06 2 2023
Accepted
29 3 2023
First published
03 4 2023
This article is Open Access
Creative Commons BY license

Chem. Commun., 2023,59, 5854-5857

Ultra-selective, ultra-clean 1D rotating-frame Overhauser effect spectroscopy

E. L. Gates, M. J. Smith, J. P. Bradley, M. Johnson, G. Widmalm, M. Nilsson, G. A. Morris, R. W. Adams and L. Castañar, Chem. Commun., 2023, 59, 5854 DOI: 10.1039/D3CC00550J

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