Issue 6, 2022

Amine-boranes reactions promoted by lanthanide(ii) ions

Abstract

The catalytic activity in amine-borane dehydrogenation is shown for the first time for Ln(II) species using complexes [{(p-tBu-C6H4)2CH}2M·L] (M = Yb, Sm, L = (DME)2, TMEDA). The protonation of M(II)–C bonds with HNR1R2BH3 affords amidoborane complexes [M(NR1R2BH3)2L], which under excess HNMe2BH3 transform to [NMe2BH2NMe2BH3] derivatives, both serving as the dehydrocoupling intermediates.

Graphical abstract: Amine-boranes reactions promoted by lanthanide(ii) ions

Supplementary files

Article information

Article type
Communication
Submitted
15 11 2021
Accepted
17 12 2021
First published
17 12 2021

Chem. Commun., 2022,58, 859-862

Amine-boranes reactions promoted by lanthanide(II) ions

V. A. Kirkina, A. A. Kissel, A. N. Selikhov, Y. V. Nelyubina, O. A. Filippov, N. V. Belkova, A. A. Trifonov and E. S. Shubina, Chem. Commun., 2022, 58, 859 DOI: 10.1039/D1CC06401K

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