Themed collection Highlights in battery technology


Approaching convergence in the electrochemical mechanism of aqueous Zn–MnO2 sustainable batteries
Manganese oxide cathodes are quite appealing when considering aqueous rechargeable zinc-ion batteries (ARZIBs) and long-term cycling for stationary energy storage systems.
EES Batteries, 2025,1, 665-671
https://doi.org/10.1039/D5EB00069F

Circular battery design: investing in sustainability and profitability
The market share of low-cost battery chemistries, which offer little to no recycling profitability with current methods, is growing. Design for circularity could be the key to reducing costs and enhancing sustainability for these batteries.
Energy Environ. Sci., 2024,17, 8529-8544
https://doi.org/10.1039/D4EE03418J

Insights into solvent molecule design for advanced electrolytes in lithium metal batteries
This review summarizes the distinct structural features of various types of solvents, including esters, ethers, and other solvent molecules containing heteroatoms, along with their applications in the electrolytes of lithium metal batteries.
EES Batteries, 2025, Advance Article
https://doi.org/10.1039/D5EB00174A

A comprehensive review of lithium-ion battery components degradation and operational considerations: a safety perspective
This review explores degradation pathways, failure risks, and mitigation strategies in lithium-ion batteries, with focus on safety and operation in EVs, ESS, and extreme military environments.
Energy Adv., 2025,4, 820-877
https://doi.org/10.1039/D5YA00065C

Separator membranes for aqueous zinc–manganese oxide batteries: a comprehensive review on experimental results and theoretical simulations
This work provides a review on theoretical simulation and experimental results in separator membranes for zinc–manganese oxide batteries, where this battery system has gained interest as an alternative to lithium-ion batteries.
Sustainable Energy Fuels, 2025,9, 1432-1446
https://doi.org/10.1039/D4SE01817F
Corrosion of metallic anodes in aqueous batteries
This review thoroughly discusses the corrosion behaviors of various metallic anodes in aqueous metal batteries. It also provides a comprehensive overview of corrosion prevention tactics and characterization methods.
Energy Environ. Sci., 2025,18, 2050-2094
https://doi.org/10.1039/D5EE00075K
Strategies of interfacial chemistry manipulated zinc deposition towards high-energy and long-cycle-life aqueous anode-free zinc metal batteries
This review summarizes the strategies for achieving efficient zinc plating/stripping based on interfacial chemistry manipulation in anode-free zinc metal batteries.
Energy Environ. Sci., 2025,18, 545-578
https://doi.org/10.1039/D4EE04525D
Towards intelligent electric vehicle power batteries and multi-scenario application vehicle operation safety charging strategies: a review
Herein, we introduce the characteristics of different charging strategies and their equalization control technologies based on battery cells and modules and present an overview of the charging mode of the whole vehicle in detail.
Sustainable Energy Fuels, 2024,8, 3496-3523
https://doi.org/10.1039/D4SE00291A

Beyond lithium lanthanum titanate: metal-stable hafnium perovskite electrolytes for solid-state batteries
This study shows the possibility of using lithium hafnium titanate as a potential stable metal battery electrolyte.
EES Batteries, 2025,1, 1114-1121
https://doi.org/10.1039/D5EB00089K

Sodium-ion battery research @ BAM (I): investigating the thermal runaway behaviour of commercial sodium-ion battery cells
Current commercial SIB-cells can go in TR even at a low SOC of 30% and, thus, should be classified alongside LIB-cells. Higher SOCs worsen TR-effects, lowering onset temperature, increasing peak pressure, and raising the risk of jelly roll ejection.
Sustainable Energy Fuels, 2025, Advance Article
https://doi.org/10.1039/D5SE00687B

Key factors influencing the plateau region in N-doped hard carbon for sodium storage
We propose a dominant layer-filling mechanism to explain Na+ storage in the plateau region, attributing it to the filling of disordered carbon layers rather than the filling of nano-/micro-pores.
EES Batteries, 2025, Advance Article
https://doi.org/10.1039/D5EB00168D

Cu substrate as a bi-directional kinetic promoter for high-efficiency four-electron Sn aqueous batteries
Cu–Sn affinity lowers barriers for Sn plating and Sn(OH)3− oxidation, promoting efficient four-electron redox in aqueous Sn batteries.
EES Batteries, 2025, Advance Article
https://doi.org/10.1039/D5EB00176E

Sodium in situ modulated phase transition to construct iron/vanadium bimetallic sulfide anodes for “fast-charging” sodium-ion batteries
Iron/vanadium bimetallic sulfides are constructed by in situ modulating phase structure under high-temperature sulfuration conditions with the help of the electron-promoting effect of sodium species, achieving fast-charging sodium storage.
EES Batteries, 2025, Advance Article
https://doi.org/10.1039/D5EB00127G

Current distribution simulation of parallel-connected modules using degraded lithium-ion battery cells
This study introduces a method for determining current distribution during the charging of modules composed of parallel-connected lithium-ion battery cells exhibiting varying levels of degradation.
EES Batteries, 2025,1, 913-921
https://doi.org/10.1039/D5EB00103J

Multifunctional scavengers in an MOF-Al2O3-based Janus separator for high-voltage lithium batteries
The scavenging mechanism for H2O and HF by HKUST-1 and Al2O3 nanoparticles, respectively, in a double-scavenger Janus separator.
EES Batteries, 2025,1, 840-852
https://doi.org/10.1039/D5EB00017C

Interphase design from ionic liquid cation mixtures and multi-mode surface analysis for safe and stable Na metal batteries
Mixed-cation ILs containing P1444+ significantly improve sodium cycling stability, revealed through in situ techniques studying interfacial nano-structuring.
EES Batteries, 2025,1, 853-866
https://doi.org/10.1039/D5EB00052A

Full life cycle assessment of an industrial lead–acid battery based on primary data
This work shows why the environmental impact of batteries should always be investigated on an application-specific basis.
Energy Adv., 2025,4, 910-929
https://doi.org/10.1039/D5YA00057B

The geostrategic race for leadership in future electric vehicle battery technologies
This study highlights global innovation imbalances in future electric vehicle battery technologies, with regional policies and differing innovation capabilities driving disparities in leadership and competitiveness.
Energy Environ. Sci., 2025,18, 6117-6130
https://doi.org/10.1039/D5EE00301F

Probing the electrochemical behaviour of lithium imide as an electrolyte for solid-state batteries
Lithium imide is an underexplored candidate for an all-solid-state battery electrolyte. Here it is shown to possess many desirable properties and unusual electrochemical behaviour, alongside its first operation in two lithium metal batteries.
EES Batteries, 2025,1, 527-540
https://doi.org/10.1039/D5EB00058K

Insights into the chemical and electrochemical behavior of halide and sulfide electrolytes in all-solid-state batteries
Understanding the chemical and electrochemical behavior of halide and sulfide electrolytes offers a straightforward and effective approach to improving the interface of halide-based solid-state batteries.
Energy Adv., 2025,4, 518-529
https://doi.org/10.1039/D4YA00618F

Operando phase transition mapping of the negative electrode of a Li-ion 18 650 battery at high C-rates through fast synchrotron XRD-CT measurements
In situ/operando X-ray diffraction computed tomography experiments have been conducted on commercial cells during non-stop high C-rate cycling. The changes in the negative electrode were mapped by comparing phase transitions and lithiation distribution of electrodes in an aged and a pristine cell.
Sustainable Energy Fuels, 2025,9, 1848-1858
https://doi.org/10.1039/D4SE00358F

Enhancing solid-state battery performance with spray-deposited gradient composite cathodes
Bi-nozzle spray deposition was used to manufacture graded LFP/PEO composite cathodes which are proven to reduce interface resistance between the electrode and solid electrolyte leading to improved capacity retention and rate performance.
Sustainable Energy Fuels, 2025,9, 1379-1386
https://doi.org/10.1039/D4SE01736F

Voltage and temperature effects on low cobalt lithium-ion battery cathode degradation
Temperature accelerates the voltage-driven degradation mechanisms in low-cobalt lithium-ion battery cathodes.
Energy Adv., 2025,4, 304-319
https://doi.org/10.1039/D4YA00530A
A flexible phase change material based on hydrated salts exhibits high stability and insulation properties for battery thermal management
A flexible phase change material based on inorganic hydrated salts, featuring high enthalpy, flexibility, insulation, and flame retardancy, suitable for lithium battery thermal management.
Sustainable Energy Fuels, 2025,9, 804-815
https://doi.org/10.1039/D4SE00871E

Non-woven pitch-based carbon fiber electrodes for low-cost redox flow battery
The low-cost and sustainable non-woven carbon fibers produced from petroleum pitch using a melt-blowing process are shown to be an ideal alternative to expensive polyacrylonitrile-based carbon felt electrode material for redox flow batteries.
Sustainable Energy Fuels, 2025,9, 198-207
https://doi.org/10.1039/D4SE01124D
Atom-dominated relay catalysis of high-entropy MXene promotes cascade polysulfide conversion for lithium–sulfur batteries
The high-entropy TiVNbMoC3 MXene, with its atom-dominated relay catalysis effect and resilient lattice configuration, promotes a cascade of sulfur conversions and guides uniform Li+ deposition, enabling shuttle-free and dendrite-free Li–S batteries.
Energy Environ. Sci., 2024,17, 7735-7748
https://doi.org/10.1039/D4EE03402C

The origins of critical deformations in cylindrical silicon based Li-ion batteries
Correlative neutron and X-ray imaging unravels the causes of localized defects in Li-ion batteries containing a silicon-graphite based anode.
Energy Environ. Sci., 2024,17, 5048-5059
https://doi.org/10.1039/D4EE00590B

Insights into lithium inventory quantification of LiNi0.5Mn1.5O4–graphite full cells
A systematic methodology for the quantification of lithium inventory is developed and the degradation mechanisms of high-voltage lithium batteries are revealed.
Energy Environ. Sci., 2024,17, 4263-4272
https://doi.org/10.1039/D4EE00842A
Engineering a zinc anode interphasial chemistry for acidic, alkaline and non-aqueous electrolytes
By employing 3,5-bis(trifluoromethyl) pyrazole (TFMP) as an electrolyte additive in both aqueous and non-aqueous mediums, a versatile interphase strategy is achieved. This facilitates stable Zn anodes with improved efficiency and longer cycling life.
Energy Environ. Sci., 2024,17, 2468-2479
https://doi.org/10.1039/D4EE00062E