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The mesoporous framework [Cu3(L)(H2O)3]·(DMF)35·(H2O)35 (NOTT-119) shows on desolvation a BET surface area of 4118(200) m2 g−1, a pore volume of 2.35 cm3 g−1, a total H2 uptake of 101 mg g−1 at 60 bar, 77 K and a total CH4 uptake of 327 mg g−1 at 80 bar, 298 K.

Graphical abstract: A mesoporous metal–organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra

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