Issue 9, 2016

Rhodium/copper-cocatalyzed annulation of benzylamines with diazo compounds: access to fused isoquinolines

Abstract

Benzylamine has been applied as an arene source in C–H activation and coupling with different types of diazo compounds, leading to the synthesis of fused isoquinolines. This occurs via a mild synergistic rhodium- and copper-catalyzed process. Moreover, ecofriendly O2 has been used as a terminal oxidant with high efficiency.

Graphical abstract: Rhodium/copper-cocatalyzed annulation of benzylamines with diazo compounds: access to fused isoquinolines

Supplementary files

Article information

Article type
Research Article
Submitted
22 Мау. 2016
Accepted
22 Шіл. 2016
First published
26 Шіл. 2016

Org. Chem. Front., 2016,3, 1159-1162

Rhodium/copper-cocatalyzed annulation of benzylamines with diazo compounds: access to fused isoquinolines

Q. Wang and X. Li, Org. Chem. Front., 2016, 3, 1159 DOI: 10.1039/C6QO00287K

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