Issue 40, 2009
From the journal:

Chemical Communications

Iridium-catalyzed enantioselective hydrogenation of vinyl boronates†

Alexander Paptchikhine,a   Pradeep Cheruku,a   Mattias Engmana  and  Pher G. Andersson*a  

* Corresponding authors

a Dept. of Biochemistry and Organic Chemistry, Uppsala University, Husargatan 3, Uppsala, Sweden
E-mail: pher.andersson@biorg.uu.se
Fax: +46 18-471 38 18
Tel: +46 18-471 38 16

Abstract

The first Ir-catalyzed asymmetric hydrogenations of vinyl boronates have been performed using low catalyst loadings (0.5 mol%) and pressure (as low as 1 bar). Good selectivities (76–98% ee) were obtained for a range of substrates.

Graphical abstract: Iridium-catalyzed enantioselective hydrogenation of vinyl boronates

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B912590F
Article type
Communication
Submitted
25 Мау. 2009
Accepted
24 Там. 2009
First published
15 Қыр. 2009

Chem. Commun., 2009, 5996-5998

Permissions

Request permissions

Iridium-catalyzed enantioselective hydrogenation of vinyl boronates

A. Paptchikhine, P. Cheruku, M. Engman and P. G. Andersson, Chem. Commun., 2009, 5996 DOI: 10.1039/B912590F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements