Volume 247, 2023

Photoelectrocatalyzed undirected C–H trifluoromethylation of arenes: catalyst evaluation and scope

Abstract

During the last few years, photoelectrocatalysis has evolved as an increasingly viable tool for molecular synthesis. Despite several recent reports on the undirected C–H functionalization of arenes, thus far, a detailed comparison of different catalysts is still missing. To address this, more than a dozen different mediators were employed in the trifluoromethylation of (hetero-)arenes to compare them in their efficacies.

Graphical abstract: Photoelectrocatalyzed undirected C–H trifluoromethylation of arenes: catalyst evaluation and scope

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Article information

Article type
Paper
Submitted
10 4 2023
Accepted
05 6 2023
First published
05 6 2023
This article is Open Access
Creative Commons BY license

Faraday Discuss., 2023,247, 79-86

Photoelectrocatalyzed undirected C–H trifluoromethylation of arenes: catalyst evaluation and scope

J. Struwe and L. Ackermann, Faraday Discuss., 2023, 247, 79 DOI: 10.1039/D3FD00076A

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