Issue 1, 2017

Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

Abstract

The chiral expression of a molecule on a surface is driven from a random solid solution on Cu(100) to a racemic crystal on a Sn/Cu(100) alloy. Density functional theory simulations reveal how the growth of the racemate is influenced by the underlying surface.

Graphical abstract: Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

Supplementary files

Article information

Article type
Communication
Submitted
18 8 2016
Accepted
29 11 2016
First published
29 11 2016

Chem. Commun., 2017,53, 130-133

Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

J. D. Fuhr, M. W. van der Meijden, L. J. Cristina, L. M. Rodríguez, R. M. Kellogg, J. E. Gayone, H. Ascolani and M. Lingenfelder, Chem. Commun., 2017, 53, 130 DOI: 10.1039/C6CC06785A

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