Issue 25, 2021

C–H and C–F coordination of arenes in neutral alkaline earth metal complexes

Abstract

A series of neutral magnesium and calcium complexes bearing an extremely bulky diamido ligand have been synthesised and crystallographically characterised. A number of these complexes feature rare group 2 metal⋯aromatic interactions, such as the η6-coordination of benzene and ‘agostic-like’ C–H coordination, the latter previously unseen in neutral Mg and Ca complexes.

Graphical abstract: C–H and C–F coordination of arenes in neutral alkaline earth metal complexes

Supplementary files

Article information

Article type
Communication
Submitted
11 5 2021
Accepted
14 6 2021
First published
15 6 2021

Dalton Trans., 2021,50, 8685-8689

C–H and C–F coordination of arenes in neutral alkaline earth metal complexes

J. S. McMullen, A. J. Edwards and J. Hicks, Dalton Trans., 2021, 50, 8685 DOI: 10.1039/D1DT01532J

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