Issue 23, 2016

Anion-templated 2D frameworks from hexahydroxytriphenylene

Abstract

Hexahydroxytriphenylene (HHTP) forms 2D frameworks through O–H⋯anion hydrogen bonds with a range of anions. In all cases, 1 : 1 co-crystals of HHTP and tetraalkylammonium·anion salts are obtained, which have a layered 2D structure. When HSO4 was used as anion, an unprecedented methylation reaction was observed giving crystals containing the methylsulfate anion (MeOSO3).

Graphical abstract: Anion-templated 2D frameworks from hexahydroxytriphenylene

Supplementary files

Article information

Article type
Communication
Submitted
03 feb. 2016
Accepted
27 mar. 2016
First published
06 apr. 2016
This article is Open Access
Creative Commons BY-NC license

CrystEngComm, 2016,18, 4281-4284

Anion-templated 2D frameworks from hexahydroxytriphenylene

M. Morshedi, A. C. Willis and N. G. White, CrystEngComm, 2016, 18, 4281 DOI: 10.1039/C6CE00297H

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