Issue 45, 2020

Alkali-metal- and halide-free dinuclear mixed-valent samarium and europium complexes

Abstract

We describe the synthesis of mixed-valent (Ln(II)/Ln(III)) dilanthanide complexes supported by a calix[4]pyrrole ligand. The complexes are obtained by one-electron reduction of Ln(III)/Ln(III) complexes and are alkali-metal- and halide-free. The complexes are designed to activate small molecules by taking advantage of both the base and the one-electron reductant contained in their structure. We demonstrate a proof-of-principle concept of this mechanism by activating water and silanol.

Graphical abstract: Alkali-metal- and halide-free dinuclear mixed-valent samarium and europium complexes

Supplementary files

Article information

Article type
Communication
Submitted
23 Մրտ 2020
Accepted
08 Ապր 2020
First published
08 Ապր 2020

Dalton Trans., 2020,49, 16059-16061

Alkali-metal- and halide-free dinuclear mixed-valent samarium and europium complexes

N. F. M. Mukthar, N. D. Schley and G. Ung, Dalton Trans., 2020, 49, 16059 DOI: 10.1039/D0DT01095B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements