Thiazolothiazole-linked porous organic polymers

Xiang Zhu; Chengcheng Tian; Tian Jin; Jitong Wang; Shannon M. Mahurin; Wenwen Mei; Yan Xiong; Jun Hu; Xinliang Feng; Honglai Liu; Sheng Dai

doi:10.1039/C4CC07255C

Thiazolothiazole-linked porous organic polymers†

Xiang Zhu,^a Chengcheng Tian,^a Tian Jin,^a Jitong Wang,^a Shannon M. Mahurin,^b Wenwen Mei,^a Yan Xiong,^a Jun Hu,^a Xinliang Feng,*^c Honglai Liu*^a and Sheng Dai*^b

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^a State Key Laboratory of Chemical Engineering and Department of Chemistry, East China University of Science and Technology, Shanghai, China
E-mail: hlliu@ecust.edu.cn
Fax: +86 021-64252921
Tel: +86 21 6425 2921

^b Chemical Science Division, Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831, USA
E-mail: dais@ornl.gov
Fax: +1 865 576 5235
Tel: +1 865 576 7307

^c Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany
E-mail: feng@mpip-mainz.mpg.de
Fax: +49 6131 379 350
Tel: +49 6131 379 150

Abstract

Thiazolothiazole-linked porous organic polymers have been synthesized from a facile catalyst-free condensation reaction between aldehydes and dithiooxamide under solvothermal conditions. The resultant porous frameworks exhibit a highly selective uptake of CO₂ over N₂ under ambient conditions.

This article is part of the themed collection: Celebrating the ChemComm Emerging Investigator Lectureship Winners

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Thiazolothiazole-linked porous organic polymers†

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