Issue 95, 2014
From the journal:

Chemical Communications

Metal-free aminoamidiniumation employing N-iodosuccinimide: facile syntheses of bicyclic imidazolidiniums and cyclic vicinal diamines†

Jun Zhang,*a   Gengtao Zhang,a   Weijie Wu,a   Xuejun Zhanga  and  Min Shiab  

* Corresponding authors

a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Mei Long Road, Shanghai 200237, China
E-mail: zhangj@ecust.edu.cn
Tel: +86 021 64252995

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China
Tel: +86 021 64252995

Abstract

NIS-mediated aminoamidiniumation has been developed for the syntheses of bicyclic imidazolidinium salts, which could be readily converted into cyclic vicinal diamines.

Graphical abstract: Metal-free aminoamidiniumation employing N-iodosuccinimide: facile syntheses of bicyclic imidazolidiniums and cyclic vicinal diamines

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Article information

DOI
https://doi.org/10.1039/C4CC07082H
Article type
Communication
Submitted
08 Sep 2014
Accepted
09 Oct 2014
First published
09 Oct 2014

Chem. Commun., 2014,50, 15052-15054

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Metal-free aminoamidiniumation employing N-iodosuccinimide: facile syntheses of bicyclic imidazolidiniums and cyclic vicinal diamines

J. Zhang, G. Zhang, W. Wu, X. Zhang and M. Shi, Chem. Commun., 2014, 50, 15052 DOI: 10.1039/C4CC07082H

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