Issue 77, 2018

Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

Abstract

The syntheses, structural, and magnetic characterization of three new organometallic Ce complexes stabilized by PyCp22− (PyCp22− = [2,6-(CH2C5H3)2C5H3N]2−) are reported. Complex 1 provides the first example of a crystallographically characterized unsupported Ce–Fe bond in a molecular compound. Results from IR spectroscopy and computational analyses suggest weaker Fe → Ce electron-donation than in a previously reported Dy–Fe bonded species.

Graphical abstract: Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

Supplementary files

Article information

Article type
Communication
Submitted
02 srp 2018
Accepted
04 ruj 2018
First published
04 ruj 2018

Chem. Commun., 2018,54, 10893-10896

Author version available

Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex

C. P. Burns, X. Yang, S. Sung, J. D. Wofford, N. S. Bhuvanesh, M. B. Hall and M. Nippe, Chem. Commun., 2018, 54, 10893 DOI: 10.1039/C8CC05243C

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