Issue 5, 2020

Introducing the Tishchenko reaction into sustainable polymer chemistry

Abstract

Taking advantage of the structural characteristics of lignin-derived phenolic compounds, a combination of the Williamson and Tishchenko reactions produced a series of new α,ω-diene functionalized carboxylic ester monomers from both petrochemical and renewable resources, which were applicable in subsequent thiol–ene click and acyclic diene metathesis (ADMET) polymerizations, providing a series of poly(thioether esters) and unsaturated aromatic–aliphatic polyesters with high molecular weights.

Graphical abstract: Introducing the Tishchenko reaction into sustainable polymer chemistry

Supplementary files

Article information

Article type
Communication
Submitted
14 नवम्बर 2019
Accepted
23 दिसम्बर 2019
First published
23 दिसम्बर 2019

Green Chem., 2020,22, 1542-1547

Introducing the Tishchenko reaction into sustainable polymer chemistry

T. Ren, Q. Chen, C. Zhao, Q. Zheng, H. Xie and M. North, Green Chem., 2020, 22, 1542 DOI: 10.1039/C9GC03926K

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