Issue 9, 2018

Asymmetric total syntheses of callistrilones B, G and J

Abstract

A very concise approach for the first asymmetric and scalable total syntheses of callistrilones B, G and J has been developed. These syntheses proceeded in only 3–4 steps from the commercially available (−)-α-phellandrene (8), without the need for protecting groups. The key feature of the syntheses was a biomimetic, diastereo- and regioselective oxidative [3 + 2] cycloaddition.

Graphical abstract: Asymmetric total syntheses of callistrilones B, G and J

Supplementary files

Article information

Article type
Research Article
Submitted
04 פבר 2018
Accepted
14 מרץ 2018
First published
15 מרץ 2018

Org. Chem. Front., 2018,5, 1506-1510

Asymmetric total syntheses of callistrilones B, G and J

L. Hu, M. Cheng, J. Cao, L. Zhong, Y. Hu, Y. Wang, L. Wang, W. Ye and C. Li, Org. Chem. Front., 2018, 5, 1506 DOI: 10.1039/C8QO00130H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements