Issue 47, 2023

Peripheral nucleic bases boost H2 production by synthetic molecular catalysts in acidic water

Abstract

The strategic inclusion of nucleic bases adenine, cytosine, and thymine, in the form of outer coordination sphere, positively impacts the electro- and photocatalytic H2 production by cobaloxime cores. These cobaloxime derivatives showcased their optimal H2 production in acidic media due to specific protonation of adenine and cytosine below pH 5.0.

Graphical abstract: Peripheral nucleic bases boost H2 production by synthetic molecular catalysts in acidic water

Supplementary files

Article information

Article type
Communication
Submitted
28 פבר 2023
Accepted
15 מאי 2023
First published
16 מאי 2023

Chem. Commun., 2023,59, 7243-7246

Peripheral nucleic bases boost H2 production by synthetic molecular catalysts in acidic water

S. Das, C. Das, N. A. Shah, S. Ghorai, P. Majumder and A. Dutta, Chem. Commun., 2023, 59, 7243 DOI: 10.1039/D3CC00964E

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