Issue 47, 2023
From the journal:

Chemical Communications

Polysulfide synthesis via visible-light-induced heteroarene-migratory dithiosulfonylation reaction†

Baoxu Wang, ORCID logo a   Zijing Hu,a   Lu Huang,a   Xiaorui Ren,a   Qianwen Gao ORCID logo *a  and  Xi Wang ORCID logo *ab  

* Corresponding authors

a College of Chemistry and Chemical Engineering, State Key Laboratory of Chemo/Biosensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, Hunan University, Changsha 410082, China
E-mail: cccewangxi@hnu.edu.cn, gaoqw@hnu.edu.cn

b Greater Bay Area Institute for Innovation, Hunan University, Guangzhou 511300, P. R. China

Abstract

A photocatalyzed heteroarene-migratory dithiosulfonylation of alkene-tethered sulfone using dithiosulfonate (ArSO2-SSR) has been reported, featuring mild conditions, and high atom economy. The resulting products can be converted into dihydrothiophenes and homoallyl disulfides, making the method highly valuable.

Graphical abstract: Polysulfide synthesis via visible-light-induced heteroarene-migratory dithiosulfonylation reaction

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Article information

DOI
https://doi.org/10.1039/D3CC01994B
Article type
Communication
Submitted
24 Apr 2023
Accepted
17 May 2023
First published
18 May 2023

Chem. Commun., 2023,59, 7247-7250

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Polysulfide synthesis via visible-light-induced heteroarene-migratory dithiosulfonylation reaction

B. Wang, Z. Hu, L. Huang, X. Ren, Q. Gao and X. Wang, Chem. Commun., 2023, 59, 7247 DOI: 10.1039/D3CC01994B

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