Issue 47, 2023

Polysulfide synthesis via visible-light-induced heteroarene-migratory dithiosulfonylation reaction

Abstract

A photocatalyzed heteroarene-migratory dithiosulfonylation of alkene-tethered sulfone using dithiosulfonate (ArSO2-SSR) has been reported, featuring mild conditions, and high atom economy. The resulting products can be converted into dihydrothiophenes and homoallyl disulfides, making the method highly valuable.

Graphical abstract: Polysulfide synthesis via visible-light-induced heteroarene-migratory dithiosulfonylation reaction

Supplementary files

Article information

Article type
Communication
Submitted
24 Apr 2023
Accepted
17 May 2023
First published
18 May 2023

Chem. Commun., 2023,59, 7247-7250

Polysulfide synthesis via visible-light-induced heteroarene-migratory dithiosulfonylation reaction

B. Wang, Z. Hu, L. Huang, X. Ren, Q. Gao and X. Wang, Chem. Commun., 2023, 59, 7247 DOI: 10.1039/D3CC01994B

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