Issue 10, 2024

Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates

Abstract

Numerous industrial processes utilise gaseous chemical feedstocks to produce useful chemical products. Atmospheric and other small molecule gases, including anthropogenic waste products (e.g. carbon dioxide), can be viewed as sustainable building blocks to access value-added chemical commodities and materials. While transition metal complexes have been well documented in the reduction and transformation of these substrates, molecular complexes of the terrestrially abundant alkaline earth metals have also demonstrated promise with remarkable reactivity reported towards an array of industrially relevant gases over the past two decades. This review covers low oxidation state and hydrido group 2 complexes and their role in the reduction and transformation of a selection of important gaseous substrates towards value-added chemical products.

Graphical abstract: Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates

Article information

Article type
Review Article
Submitted
30 janv. 2024
First published
10 avr. 2024

Chem. Soc. Rev., 2024,53, 5054-5082

Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates

M. J. Evans and C. Jones, Chem. Soc. Rev., 2024, 53, 5054 DOI: 10.1039/D4CS00097H

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