Issue 39, 2023

Metal-ion doping in metal–organic-frameworks: modulating the electronic structure and local coordination for enhanced oxygen evolution reaction activity

Abstract

The doping of metal–organic frameworks (MOFs) with metal-ions has emerged as a powerful strategy for enhancing their catalytic performance. Doping allows for the tailoring of the electronic structure and local coordination environment of MOFs, thus imparting on them unique properties and enhanced functionalities. This frontier article discusses the impact of metal-ion doping on the electronic structure and local coordination of MOFs, highlighting the effects on their electrocatalytic properties in relation to the oxygen evolution reaction (OER). The fundamental mechanisms underlying these modifications are explored, while recent advances, challenges, and prospects in the field are discussed. In addition, experimental techniques that can be applied to tackle the realization of effective metal-ion doping of MOFs are also noted briefly.

Graphical abstract: Metal-ion doping in metal–organic-frameworks: modulating the electronic structure and local coordination for enhanced oxygen evolution reaction activity

Article information

Article type
Frontier
Submitted
27 juil. 2023
Accepted
10 sept. 2023
First published
25 sept. 2023

Dalton Trans., 2023,52, 13852-13857

Metal-ion doping in metal–organic-frameworks: modulating the electronic structure and local coordination for enhanced oxygen evolution reaction activity

N. K. Shrestha, S. A. Patil, A. S. Salunke, A. I. Inamdar, H. Kim and H. Im, Dalton Trans., 2023, 52, 13852 DOI: 10.1039/D3DT02405A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements