Issue 97, 2023

Photoinduced reductive Reformatsky reaction of α-haloesters and aldehydes or ketones by cooperative dual-metal catalysis

Abstract

A photoinduced reductive Reformatsky reaction by cooperative dual-metal catalysis is described. This methodology enables the implementation of this venerable reaction in environmentally friendly conditions, obviating the need for a stoichiometric amount of metals. A broad range of synthetically useful β-hydroxy esters can be efficiently prepared in moderate to high yields using this protocol.

Graphical abstract: Photoinduced reductive Reformatsky reaction of α-haloesters and aldehydes or ketones by cooperative dual-metal catalysis

Supplementary files

Article information

Article type
Communication
Submitted
21 sept. 2023
Accepted
02 nov. 2023
First published
09 nov. 2023

Chem. Commun., 2023,59, 14427-14430

Photoinduced reductive Reformatsky reaction of α-haloesters and aldehydes or ketones by cooperative dual-metal catalysis

Q. Chen, L. Mao, Y. Pan, H. Cai, X. Zhang, F. Zhang, A. Ma, J. Peng and Y. Tu, Chem. Commun., 2023, 59, 14427 DOI: 10.1039/D3CC04671K

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