Issue 53, 2022

Substitution at boron in BODIPYs

Abstract

Recent synthetic achievements have led to 4,4-disubstituted-4-bora-3a,4a-diaza-s-indacenes (BODIPYs) with varying substituents at the meso, pyrrolic and/or boron sites, with each influencing photophysical properties and utility. This Feature article gives an overview of chemistry at the boron atom in BODIPYs, highlighting our contributions that evolved from synthetic curiosities and now offer this dipyrrolic skeleton potential across a wider range of applications. We first summarise preparative routes to BODIPYs through complexation of boron with the dipyrrinato ligand. The role of boron in protecting dipyrrins is then discussed, followed by strategies by which to achieve facile substitution at the boron atom.

Graphical abstract: Substitution at boron in BODIPYs

Article information

Article type
Feature Article
Submitted
26 avr. 2022
Accepted
09 juin 2022
First published
20 juin 2022

Chem. Commun., 2022,58, 7351-7359

Substitution at boron in BODIPYs

R. L. Gapare and A. Thompson, Chem. Commun., 2022, 58, 7351 DOI: 10.1039/D2CC02362H

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