Issue 65, 2022

Photoinduced, copper-catalysed direct perfluoroalkylation of heteroarenes

Abstract

An efficient and general process is reported for the photoinduced, copper-catalysed direct perfluoroalkylation of C–H bonds in a broad range of heteroarenes with commercially available perfluoroalkyl iodides. This redox neutral process is simply based on the use of [Cu(bcp)DPEPhos]PF6 as the photoredox catalyst in the presence of potassium acetate and smoothly operates at room temperature.

Graphical abstract: Photoinduced, copper-catalysed direct perfluoroalkylation of heteroarenes

Supplementary files

Article information

Article type
Communication
Submitted
18 avr. 2022
Accepted
12 juil. 2022
First published
16 juil. 2022

Chem. Commun., 2022,58, 9080-9083

Photoinduced, copper-catalysed direct perfluoroalkylation of heteroarenes

H. Baguia, J. Beaudelot, C. Moucheron and G. Evano, Chem. Commun., 2022, 58, 9080 DOI: 10.1039/D2CC02146C

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