Issue 94, 2021

Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites

Abstract

Fluorine, as the most electronegative element, can replace the oxygen ligands of functional groups under given conditions. These fluoride groups are more or less different from the pure oxide groups in composition, symmetry, polarizability, transmittancy, etc. The rational use of these differences is expected to improve the probability of noncentrosymmetric structures and the comprehensive performance of second-harmonic-generation (SHG) materials. In this feature article, we introduce the recent developments in fluoride selenite and tellurite SHG materials together with highlighting our contributions, including Se(IV) and Te(IV) compounds with (i) d0 transition metal oxyfluoride octahedron, (ii) IIIA metal oxyfluoride octahedron, (iii) fluoride lone pair cation polyhedron, and (iv) other fluoride polyhedron. The future perspectives of fluoride selenite and tellurite SHG materials are also discussed.

Graphical abstract: Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites

Article information

Article type
Feature Article
Submitted
29 août 2021
Accepted
21 oct. 2021
First published
21 oct. 2021

Chem. Commun., 2021,57, 12575-12586

Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites

F. Kong, T. Jiang and J. Mao, Chem. Commun., 2021, 57, 12575 DOI: 10.1039/D1CC04818J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements