Solid state mononuclear divalent nickel spin crossover complexes

Abstract

Spin crossover complexes containing 3d⁴–3d⁷ transition metal ions with tunable electronic configurations in appropriate ligand field environments have been extensively investigated. In contrast, the development of 3d⁸ divalent nickel complexes displaying such a spin crossover behavior is far behind. The increasing number of X-ray single crystal structures along with magnetic evidence and thermodynamic equilibrium indicate that bistable divalent nickel complexes are gradually recognized to be a formal member of the “spin crossover family”. Unfortunately, the rarity of nickel spin crossover complexes is occasionally mentioned. This Perspective article highlights examples of mononuclear 3d⁸ nickel spin crossover complexes in dynamic rearrangements with characterized solid state structures from the viewpoint of types of ligands utilized.