Issue 9, 2019

Microwave-assisted synthesis of urea-containing zirconium metal–organic frameworks for heterogeneous catalysis of Henry reactions

Abstract

Here we report the facile preparation of a urea-containing UiO-68 isoreticular zirconium metal–organic framework (MOF) with mixed dicarboxylate struts by utilizing a microwave-assisted heating method. It can work as an efficient hydrogen-bond-donating heterogeneous catalyst for Henry reactions of benzaldehydes and nitroalkanes. This mixed strut MOF exhibits improved catalytic activity compared to the pure urea-functionalized linker based analogue.

Graphical abstract: Microwave-assisted synthesis of urea-containing zirconium metal–organic frameworks for heterogeneous catalysis of Henry reactions

Supplementary files

Article information

Article type
Communication
Submitted
20 déc. 2018
Accepted
01 févr. 2019
First published
04 févr. 2019

CrystEngComm, 2019,21, 1358-1362

Microwave-assisted synthesis of urea-containing zirconium metal–organic frameworks for heterogeneous catalysis of Henry reactions

H. Zhang, X. Gao, L. Wang, X. Zhao, Q. Li and X. Wang, CrystEngComm, 2019, 21, 1358 DOI: 10.1039/C8CE02153H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements