Issue 5, 2017

Anthroxyl-based biradical: toward the construction of highly stable multi-spin systems

Abstract

A new two-spin system having two anthroxyl radicals at the 9,10-positions of anthracene was found to be stable even after exposing it to refluxing polar-protic solvents. This stability might be derived from the spin delocalization as well as the steric protection of the spin center by the orthogonally oriented anthracene.

Graphical abstract: Anthroxyl-based biradical: toward the construction of highly stable multi-spin systems

Supplementary files

Article information

Article type
Research Article
Submitted
15 févr. 2017
Accepted
14 mars 2017
First published
22 mars 2017

Org. Chem. Front., 2017,4, 828-833

Anthroxyl-based biradical: toward the construction of highly stable multi-spin systems

Y. Hirao, A. Konishi and T. Kubo, Org. Chem. Front., 2017, 4, 828 DOI: 10.1039/C7QO00130D

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