Issue 37, 2016

Activation of CS2 by a “masked” terminal nickel sulfide

Abstract

The “masked” terminal nickel sulfide complexes [K(L)][(LtBu)NiII(S)] (LtBu = {(2,6-iPr2C6H3)NC(tBu)}2CH, L = 18-crown-6, 2,2,2-cryptand) activate CS2 to give the trithiocarbonate products [(LtBu)NiII(S,S2-CS3)] or [(S,S2-CS3)NiII{S,S2-CS2(LtBu)}], further confirming the nucleophilicity of the sulfide (S2−) ligand in these complexes.

Graphical abstract: Activation of CS2 by a “masked” terminal nickel sulfide

Supplementary files

Article information

Article type
Communication
Submitted
04 mars 2016
Accepted
25 avr. 2016
First published
26 avr. 2016

Dalton Trans., 2016,45, 14508-14510

Activation of CS2 by a “masked” terminal nickel sulfide

N. J. Hartmann, G. Wu and Trevor. W. Hayton, Dalton Trans., 2016, 45, 14508 DOI: 10.1039/C6DT00885B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements