Issue 5, 2016

Synthesis and characterization of manganese triple-decker complexes

Abstract

The use of the highly sterically demanding CpBIG ligand (CpBIG = C5(4-nBuC6H4)5) and white phosphorus (P4) enables the synthesis of new P-rich derivatives of the rare Pn ligand complexes of manganese. The obtained complexes, [{CpBIGMn}2(μ,η5:5-P5)] (2) and [{CpBIGMn}2(μ,η2:2-P2)2] (3), exhibit the highest number of P atoms in this class of manganese compounds identified by X-ray structure analyses. The EPR spectrum of the 29 VE triple-decker complex 2 shows one unpaired electron coupling with two 5/2 spin Mn nuclei.

Graphical abstract: Synthesis and characterization of manganese triple-decker complexes

Supplementary files

Article information

Article type
Paper
Submitted
08 mai 2015
Accepted
02 juin 2015
First published
04 juin 2015

Dalton Trans., 2016,45, 1962-1966

Author version available

Synthesis and characterization of manganese triple-decker complexes

S. Heinl, G. Balázs, M. Bodensteiner and M. Scheer, Dalton Trans., 2016, 45, 1962 DOI: 10.1039/C5DT01750E

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