Issue 99, 2015
From the journal:

Chemical Communications

Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations†

Hiromitsu Maeda,*a   Ayaka Fukui,a   Ryohei Yamakadoa  and  Nobuhiro Yasudab  

* Corresponding authors

a College of Pharmaceutical Sciences, Ritsumeikan University, Kusatsu 525-8577, Japan
E-mail: maedahir@ph.ritsumei.ac.jp

b Research and Utilization Division, Japan Synchrotron Radiation Research Institute, Sayo 679-5198, Japan

Abstract

A nitro-substituted dipyrrolylphenol was synthesized as a precursor of a π-electronic anion, whose phenolate (phenoxide) moiety upon deprotonation was stabilized by the hydrogen-bond-donating pyrrole NH, thus forming solid-state ion pairs with various cationic species.

Graphical abstract: Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

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Article information

DOI
https://doi.org/10.1039/C5CC07493B
Article type
Communication
Submitted
07 sept. 2015
Accepted
12 oct. 2015
First published
14 oct. 2015

Chem. Commun., 2015,51, 17572-17575

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Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

H. Maeda, A. Fukui, R. Yamakado and N. Yasuda, Chem. Commun., 2015, 51, 17572 DOI: 10.1039/C5CC07493B

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