Issue 10, 2014

Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

Abstract

In most kinetic investigations of catalytic reactions, catalytic activity is a traditionally measured kinetic parameter. However, differential selectivity measurements have many advantages for mechanistic studies. This Perspective gives an overview of the basic principles and practices of mechanistic studies based on differential selectivity measurements, including the use of artificially created competitive reactions.

Graphical abstract: Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

Supplementary files

Article information

Article type
Perspective
Submitted
14 avr. 2014
Accepted
29 mai 2014
First published
29 mai 2014

Catal. Sci. Technol., 2014,4, 3439-3457

Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

A. F. Schmidt, A. A. Kurokhtina and E. V. Larina, Catal. Sci. Technol., 2014, 4, 3439 DOI: 10.1039/C4CY00479E

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