Issue 1, 2013

A microporous metal–organic framework with both open metal and Lewis basic pyridyl sites for highly selective C2H2/CH4 and C2H2/CO2 gas separation at room temperature

Abstract

To immobilize both open metal and Lewis basic pyridyl sites into a microporous metal–organic framework, Cu6(PDC)6·2.6H2O (UTSA-50) was solvothermally synthesized and characterized. The combination of open metal sites and Lewis basic pyridyl functional sites leads to a high acetylene adsorption enthalpy of 39.4 kJ mol−1. As a result, UTSA-50 is a very promising MOF material for the highly selective separation of C2H2/CH4 and C2H2/CO2 at room temperature with the highest C2H2/CH4 separation selectivity of 68 ever reported and moderately high acetylene uptake of 91 cm−1 g−1.

Graphical abstract: A microporous metal–organic framework with both open metal and Lewis basic pyridyl sites for highly selective C2H2/CH4 and C2H2/CO2 gas separation at room temperature

Supplementary files

Article information

Article type
Paper
Submitted
31 août 2012
Accepted
15 oct. 2012
First published
16 oct. 2012

J. Mater. Chem. A, 2013,1, 77-81

A microporous metal–organic framework with both open metal and Lewis basic pyridyl sites for highly selective C2H2/CH4 and C2H2/CO2 gas separation at room temperature

H. Xu, Y. He, Z. Zhang, S. Xiang, J. Cai, Y. Cui, Y. Yang, G. Qian and B. Chen, J. Mater. Chem. A, 2013, 1, 77 DOI: 10.1039/C2TA00155A

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