Cyclic and polycyclic tellurium–tin and tellurium–lead compounds – synthesis, structures and thermal decomposition

Stephan Traut; Carsten von Hänisch; Alexander Peter Hähnel; Sven Stahl

doi:10.1039/C2CC32615A

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Cyclic and polycyclic tellurium–tin and tellurium–lead compounds – synthesis, structures and thermal decomposition†

Stephan Traut,^a Carsten von Hänisch,*^a Alexander Peter Hähnel^b and Sven Stahl^b

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* Corresponding authors

^a Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften, Philipps Universität Marburg, Hans-Meerwein-Straße, D-35032 Marburg, Germany
E-mail: haenisch@chemie.uni-marburg.de

^b Institut für Nanotechnologie, KIT, Campus Nord, Postfach 3640, Karlsruhe, Germany

Abstract

The miscellaneously substituted silyltellanes tBu₂PhSiTeSiMe₃ (1) and (Me₃Si)₃SiTeSiMe₃ were used to synthesize the cyclic tin(II) and lead(II) tellurolates [(tBu₂PhSiTe)₄M₂] (M = Sn (2), Pb (3)), [tBu₂PhSiTePbC(SiMe₃)₃]₂ (4) and the uncommon cluster compound [{(Me₃Si)₃SiTe}₄Te₂Sn₄] (5).

This article is part of the themed collection: Frontiers in Molecular Main Group Chemistry

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DOI: https://doi.org/10.1039/C2CC32615A
Article type: Communication
Submitted: 12 avr. 2012
Accepted: 23 mai 2012
First published: 07 juin 2012

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Chem. Commun., 2012,48, 6984-6986

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Cyclic and polycyclic tellurium–tin and tellurium–lead compounds – synthesis, structures and thermal decomposition

S. Traut, C. von Hänisch, A. Peter Hähnel and S. Stahl, Chem. Commun., 2012, 48, 6984 DOI: 10.1039/C2CC32615A

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Chemical Communications

Cyclic and polycyclic tellurium–tin and tellurium–lead compounds – synthesis, structures and thermal decomposition†

Abstract

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Cyclic and polycyclic tellurium–tin and tellurium–lead compounds – synthesis, structures and thermal decomposition

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