Issue 43, 2012

Diborane(4)–metal bonding: between hydrogen bridges and frustrated oxidative addition

Abstract

The metal complexes [M{HB(hpp)}2(CO)4] (M = Cr, Mo or W) and [M(cod){HB(hpp)}2Cl] (M = Rh or Ir) of the doubly-base stabilized diborane(4) ligand [HB(hpp)]2 were fully characterized and their bonding nature was investigated in detail. While bonding in the group 6 complexes predominantly occurs through the hydrogen atoms, the metal–ligand interaction in the group 9 complexes can be regarded as an early stage oxidative addition of the boron–boron bond leading to diboryl compounds.

Graphical abstract: Diborane(4)–metal bonding: between hydrogen bridges and frustrated oxidative addition

Supplementary files

Article information

Article type
Communication
Submitted
06 mars 2012
Accepted
03 avr. 2012
First published
04 avr. 2012

Chem. Commun., 2012,48, 5277-5279

Diborane(4)–metal bonding: between hydrogen bridges and frustrated oxidative addition

A. Wagner, E. Kaifer and H. Himmel, Chem. Commun., 2012, 48, 5277 DOI: 10.1039/C2CC31671D

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